Reaction of 2,6-Bis(4-azidobenzylidene)-4-methyl-cyclohexanone with Organophosphorus Reagents. Synthesis of Some Benzylidene-1, 2, 3-triazole Derivatives

References:

1

Abstract

RIPHENYLPHOSPHINE (1) reacts with 2,6-bis(4-azidobenzylidene)-4-methylcyclohexanone (4) to give the respective triphenylphosphinylidenetriaz-1-enyl (5a) and triphenylphosphinylideneamino (5b).Moreover, reaction of aryl azide (4) with trisdimethylaminophosphine (2) in refluxing toluene afforded the new products (6a, b).On the other hand, phosphorus ylides (3a-d) react with azidobenzylidene (4) to g...

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Keywords

Cyclohexanone

Chemistry

Reagent

Combinatorial chemistry

Medicinal chemistry

Organic chemistry

Catalysis

Sustainable Development Goals (SDG)

Clean water and sanitation

2010

Article

Open Access

Institution

Organometallic and Organometalloid Chemistry Department , National Research Centre, Giza, Egypt.

2-Y Citation Average

0.712

DOI

https://doi.org/10.21608/ejchem.2010.1212

Language

en

Country

Egypt

Reaction of 2,6-Bis(4-azidobenzylidene)-4-methyl-cyclohexanone with Organophosphorus Reagents. Synthesis of Some Benzylidene-1, 2, 3-triazole Derivatives

Egyptian Journal of Chemistry

L Boulos, S Maigali, = Ch

References:

1

Abstract

RIPHENYLPHOSPHINE (1) reacts with 2,6-bis(4-azidobenzylidene)-4-methylcyclohexanone (4) to give the respective triphenylphosphinylidenetriaz-1-enyl (5a) and triphenylphosphinylideneamino (5b).Moreover, reaction of aryl azide (4) with trisdimethylaminophosphine (2) in refluxing toluene afforded the new products (6a, b).On the other hand, phosphorus ylides (3a-d) react with azidobenzylidene (4) to g...